Constant Pressure

A constant pressure process is called an isobaric process. An example is a gas in a container sealed with a piston that is free to slide up and down.

If heat is added the temperature goes up and the system expands, so work is done.

The full First Law applies:

ΔEint = Q - W

The P-V diagram for this process is a horizontal line, so the work done is simply:

W = P ΔV = nR ΔT

For a monatomic ideal gas:
ΔEint =
3
2
nR ΔT

Plugging this into the First Law gives:

Q = ΔEint + W
Q =
3
2
nR ΔT + nR ΔT =
5
2
nR ΔT