Energy in the Bohr Model

Consider the energy of an electron in its orbit. The electron has a charge of -e, while the nucleus has a charge of +Ze, where Z is the atomic number of the element. The energy is then given by:

E = U + K = -kZe2/r + mv2/2

The electron is experiencing uniform circular motion, with the only force on it being the attractive force between the negative electron and the positive nucleus. Thus:

kZe2/r2 = mv2/r

Therefore mv2 = kZe2/r

Plugging this back into the energy equation gives:

E = -kZe2/r + kZe2/2r = -kZe2/2r

We have already shown that the radius is given by:

r = n2h2/4p2mkZe2

Plugging this into the energy equation gives the total energy of the nth level:

E = -2p2mk2Z2e4/n2h2

This can be written in a more compact form:

En = (-13.6 eV) Z2/n2

So, Bohr's assumption that the momentum of the electron is quantized leads directly to the result that the electron energy is quantized.