Certain materials (such as calcite) exhibit a property known as birefringence. Birefringent material affects light polarized in a particular direction differently from light polarized at 90o to that direction; it refracts light polarized one way at a different angle than it refracts light polarized the other way. Looking through a birefringent crystal at something, you see a double image.
The ordinary ray has the same speed in all directions, while the speed of the extraordinary ray depends on direction. For calcite (CaCO3) we have, in the extreme case:
nO = 1.658
nE = 1.486
We don't see this in glass because glass is amorphous - it doesn't have a crystal structure.