Sample Problem

A container of monatomic ideal gas contains just the right number of moles so that nR = 20 J/K. The gas is in state 1 such that:

P1 = 20 kPa
V1 = 100 x 10-3 m3

(a) What is the temperature T1 of the gas?










Use the ideal gas law:

PV = nRT, so:

T1 = P1V1/nR = 2000/20 = 100 K

(b) If Q = 2500 J of heat is added to the gas, and the gas expands at constant pressure, the gas will reach a new equilibrium state 2. What is the final temperature T2?










We've already seen that, at constant pressure for a monatomic ideal gas:

Q = DU + W = (3/2)nRDT + nRDT = (5/2)nRDT

Therefore DT = (2/5)Q/nR = 1000/20 = 50 K.

T2 = T1 + DT = 100 + 50 = 150 K

(c) How much work was done by the gas during the expansion?










W = nRDT = 20 * 50 = 1000 J

That equation is true only for a constant pressure process.

(d)What is the final volume V2?










One approach is to bring in the ideal gas law again:

V2 = nRT2/P2 = 20(150)/20x103 = 150 x 10-3 m3