PHYSICS 541--STATISTICAL MECHANICS I
Fall 2002

















 General Information

 Grading Policy

 Books

 Course Outline

Problem Sets

Exams
 



 
 






GENERAL INFORMATION

Instructor: Prof. Ian Affleck
Office: SCI 342E
Office Hours: Wed. 2-4 PM
                            Thurs.  4-5 PM
Phone: 617-353-2601
e-mail: py541@physics.bu.edu (best way to contact me)
Grader: Nicolas Giovambattista
Office: SCI 240
Phone: 3-4737
e-mail: ngiovamb@physics.bu.edu


Lectures: Tuesdays and Thursdays 2-3:30 PM in PRB146
Discussions: Wednesdays 4:00-5:00 in SCI 111


GRADING POLICY

Grade:

    Homework: 25%
    First Exam : 25%
    Second Exam: 25%
    Final Exam: 25%

Homework is due at the beginning of the class.  Late homework will not be accepted for credit.

First Exam : Tuesday, October 1 , 2:00-3:30, in class

Second Exam : Thursday, October 31, 2:00-3:30, in class

Final Exam: Monday, December 16, 9:00-11:00 AM


BOOKS

Required text: R.K. Pathria, Statistical Mechanics
Recommended text: M. Plischke  & B. Bergersen, Equilibrium Statistical Physics
(These are both available at the B.U. bookstore.)

Other useful books :
(These should eventually be on reserve at the Science and Engineering Library.)
Undergraduate texts:
C. Kittel and H. Kroemer, Thermal Physics
F. Reif, Fundamentals of Statistical and Thermal Physics
Graduate texts:
L.D. Landau and E.M. Lifshitz, Statistical Physics, Parts I and II
D. Chandler, Introduction to Modern Statistical Mechanics
L. Reichl, A Modern Course in Statistical Physics


COURSE OUTLINE (subject to change)














1.  Fundamental principles of Statistical Physics:
-probabilistic description of large systems
-assumption of equal a priori probabilities (ergodic hypothesis)
-statistical ensembles: the micro-canonical ensemble
-Liouville's theorem
-quantum statistics and the density matrix
-entropy and the 2nd law of thermodynamics
-thermal, mechanical and diffusive equilibrium

2.  Thermodynamics:
-thermodynamic viewpoint
-quasi-static and reversible processes
-heat engines and Carnot inequality
-Joule-Thomson process
-entropy of mixing (the Gibbs paradox)
-thermodynamic potentials: enthalpy, Helmholtz and Gibbs free energies and their importance
-Maxwell relations

3.  The Canonical and Grand Canonical Ensembles:
-equilibrium with a heat bath
-Helmholtz free energy and grand free energy: contact with thermodynamics
-fluctuations and reduction to the micro-canonical ensemble for large systems

4.  Ideal Gases I:
-Boltzmann distribution: counting the quantum states
-free energy of an ideal gas: ideal gas law
-diatomic gases: rotational and vibrational energy
-electronic and orbital angular momentum of electrons

5.  Ideal Bose Gases:
-Bose condensation
-black body radiation
-phonons in solids

6. Ideal Fermi Gases:
-heat capacity
-Pauli paramagnetism and Landau diamagnetism: the quantum Hall effect
-electrons in metals:
        -screening of Coulomb interactions
        -thermo-ionic and photo-electric effect
-white dwarf and neutron stars

7. Interacting Gases:
-virial expansion
-van der Waals equation of state
- elementary transport theory

8. First Order Phase Transitions:
-phase diagram of a solid or fluid
-first order transitions: latent heat, Clausius-Clapeyron equation
-van der Waals approach
-metastability and surface effects

9. Second Order Phase Transitions and Critical Phenomena:
-ferromagnetism
-definition of critical exponents
-mean field theory
-Landau-Ginsburg theory
-universality and scaling
-the Ising model in one and two dimensions: transfer matrix methods
-the renormalization group approach to critical phenomena


PROBLEM SETS

Problem Set 1

Problem Set 1 Solutions

Problem Set 2

Problem Set 2 Solutions

Problem Set 3

Problem Set 3 Solutions

Problem Set 4

Problem Set 4 Solutions

Problem Set 5

Problem Set 5 Solutions

Problem Set 6

Problem Set 6 Solutions (This link will not work until Thursday afternoon)

EXAMS

Exam 1 Solutions

Exam 1 supplementary question Solution

Practice problems on quantum gases

Exam 2 Solutions

practice problems

practice problem solutions

second version of second exam: solutions

final exam: solutions